| Date | 7 August 2016 — 13:13 | |
|---|---|---|
| Location | Centro Olímpico de Tênis, Parque Olímpico da Barra, Barra da Tijuca, Rio de Janeiro (Court 6) | |
| Chair Umpire | Emmanuel Joseph |  FRA |
| Seed | Competitor | NOC | Sets Won | Sets Won | Set 1 | Set 2 | |
|---|---|---|---|---|---|---|---|
| – | Mónica Puig |  PUR | 2 | 2 | 6 | 6 | |
| – | Polona Hercog |  SLO | 0 | 0 | 3 | 2 |
| Mónica Puig | Polona Hercog | |
|---|---|---|
| Sets Won | 2 | 0 |
| Set 1 | 6 | 3 |
| Set 2 | 6 | 2 |
