| Date | 7 August 2016 — 15:46 | |
|---|---|---|
| Location | Centro Olímpico de Tênis, Parque Olímpico da Barra, Barra da Tijuca, Rio de Janeiro (Court 2) | |
| Chair Umpire | Mariana Alves |  POR |
| Seed | Competitor | NOC | Sets Won | Set #1 | Set #2 | Set #3 | |
|---|---|---|---|---|---|---|---|
| 13 | Samantha Stosur |  AUS | 2 | 1 | 6 | 6 | |
| – | Jeļena Ostapenko |  LAT | 1 | 6 | 3 | 2 |
| Samantha Stosur | Jeļena Ostapenko | |
|---|---|---|
| Sets Won | 2 | 1 |
| Set #1 | 1 | 6 |
| Set #2 | 6 | 3 |
| Set #3 | 6 | 2 |
