| Date | 13 August 2016 — 17:41 | |
|---|---|---|
| Location | Centro Olímpico de Tênis, Parque Olímpico da Barra, Barra da Tijuca, Rio de Janeiro (Centre Court) | |
| Chair Umpire | Marija Čičak |  CRO |
| Seed | Competitor | NOC | Sets Won | Sets Won | Set 1 | Set 2 | Set 3 | |
|---|---|---|---|---|---|---|---|---|
| – | Mónica Puig |  PUR | 2 | 2 | 6 | 4 | 6 | |
| 2 | Angelique Kerber |  GER | 1 | 1 | 4 | 6 | 1 |
| Mónica Puig | Angelique Kerber | |
|---|---|---|
| Sets Won | 2 | 1 |
| Set 1 | 6 | 4 |
| Set 2 | 4 | 6 |
| Set 3 | 6 | 1 |
