| Date | 7 August 2016 — 15:15 | |
|---|---|---|
| Location | Centro Olímpico de Tênis, Parque Olímpico da Barra, Barra da Tijuca, Rio de Janeiro (Court 4) | |
| Chair Umpire | Tamara Vrhovec-Wójcik |  CRO |
| Seed | Competitor | NOC | Sets Won | Sets Won | Set 1 | Set 2 | Set 3 | |
|---|---|---|---|---|---|---|---|---|
| – | Nao Hibino |  JPN | 2 | 2 | 6 | 3 | 6 | |
| – | Irina Begu |  ROU | 1 | 1 | 4 | 6 | 3 |
| Nao Hibino | Irina Begu | |
|---|---|---|
| Sets Won | 2 | 1 |
| Set 1 | 6 | 4 |
| Set 2 | 3 | 6 |
| Set 3 | 6 | 3 |
