| Date | 7 August 2016 — 13:04 | |
|---|---|---|
| Location | Centro Olímpico de Tênis, Parque Olímpico da Barra, Barra da Tijuca, Rio de Janeiro (Court 1) | |
| Chair Umpire | Kelly Thomson |  GBR |
| Seed | Competitor | NOC | Sets Won | Sets Won | Set 1 | Set 2 | |
|---|---|---|---|---|---|---|---|
| 2 | Angelique Kerber |  GER | 2 | 2 | 6 | 7 | |
| – | Mariana Duque |  COL | 0 | 0 | 3 | 5 |
| Angelique Kerber | Mariana Duque | |
|---|---|---|
| Sets Won | 2 | 0 |
| Set 1 | 6 | 3 |
| Set 2 | 7 | 5 |
