| Games | Athlete/Team | Placement | |
|---|---|---|---|
| 1992 Winter Olympics | Gunda Niemann | 1 | Gold |
| Heike Warnicke | 2 | Silver | |
| Claudia Pechstein | 3 | Bronze | |
| 1994 Winter Olympics | Claudia Pechstein | 1 | Gold |
| Gunda Niemann | 2 | Silver | |
| 1998 Winter Olympics | Claudia Pechstein | 1 | Gold |
| Gunda Niemann-Stirnemann | 2 | Silver | |
| Heike Warnicke | 14 | ||
| 2002 Winter Olympics | Claudia Pechstein | 1 | Gold |
| Anni Friesinger | 6 | ||
| Daniela Anschütz | 12 | ||
| 2006 Winter Olympics | Claudia Pechstein | 2 | Silver |
| Daniela Anschütz-Thoms | 5 | ||
| Lucille Opitz | 14 | ||
| 2010 Winter Olympics | Stephanie Beckert | 2 | Silver |
| Daniela Anschütz-Thoms | 4 | ||
| Katrin Mattscherodt | DQ | ||
| 2014 Winter Olympics | Claudia Pechstein | 5 | |
| Stephanie Beckert | 8 | ||
| Bente Kraus | 11 | ||
| 2018 Winter Olympics | Claudia Pechstein | 8 |