| Date | 8 August 2016 — 13:07 | |
|---|---|---|
| Location | Centro Olímpico de Tênis, Parque Olímpico da Barra, Barra da Tijuca, Rio de Janeiro (Court 3) | |
| Chair Umpire | Miriam Bley |  GER |
| Seed | Competitor | NOC | Sets Won | Sets Won | |
|---|---|---|---|---|---|
| 8 | Svetlana Kuznetsova |  RUS | – | walkover | |
| – | Monica Niculescu |  ROU | – |
| Svetlana Kuznetsova | Monica Niculescu | |
|---|---|---|
| Sets Won | – | – |
