| Date | 6 August 2016 — 17:13 | |
|---|---|---|
| Location | Centro Olímpico de Tênis, Parque Olímpico da Barra, Barra da Tijuca, Rio de Janeiro (Court 6) | |
| Chair Umpire | Kader Nouni |  FRA |
| Seed | Competitor | NOC | Sets Won | Set #1 | Set #2 | |
|---|---|---|---|---|---|---|
| 14 | Anastasiya Pavlyuchenkova |  RUS | 2 | 6 | 6 | |
| – | Magda Linette |  POL | 0 | 0 | 3 |
| Anastasiya Pavlyuchenkova | Magda Linette | |
|---|---|---|
| Sets Won | 2 | 0 |
| Set #1 | 6 | 0 |
| Set #2 | 6 | 3 |
