| 1994 Winter Olympics |
Ukraine
|
Viktor Petrenko
|
Figure Skating
|
|
|
| 1996 Summer Olympics |
Ukraine
|
Sergey Bubka
|
Athletics
|
|
|
| 1998 Winter Olympics |
Ukraine
|
Andriy Deryzemlia
|
Biathlon
|
|
|
| 2000 Summer Olympics |
Ukraine
|
Yevhen Braslavets
|
Sailing
|
|
|
| 2002 Winter Olympics |
Ukraine
|
Olena Petrova
|
Biathlon
|
|
|
| 2004 Summer Olympics |
Ukraine
|
Denys Sylantiev
|
Swimming
|
|
144 |
| 2006 Winter Olympics |
Ukraine
|
Nataliya Yakushenko
|
Luge
|
|
|
| 2008 Summer Olympics |
Ukraine
|
Yana Klochkova
|
Swimming
|
Did not compete. |
33 |
| 2010 Summer Youth Olympics |
Ukraine
|
Alina Komashchuk
|
Fencing
|
|
|
| 2010 Winter Olympics |
Ukraine
|
Liliya Ludan
|
Luge
|
|
79 |
| 2012 Summer Olympics |
Ukraine
|
Roman Hontiuk
|
Judo
|
|
193 |
| 2012 Winter Youth Olympics |
Ukraine
|
Anton Dukach
|
Luge
|
|
62 |
| 2014 Summer Youth Olympics |
Ukraine
|
Yuliia Miiuts
|
Taekwondo
|
|
194 |
| 2014 Winter Olympics |
Ukraine
|
Valentyna Shevchenko
|
Cross Country Skiing
|
|
75 |
| 2016 Summer Olympics |
Ukraine
|
Mykola Milchev
|
Shooting
|
|
195 |
| 2016 Winter Youth Olympics |
Ukraine
|
Vlad Heraskevych
|
Skeleton
|
|
66 |
| 2018 Summer Youth Olympics |
Ukraine
|
Mykhaylo Kokhan
|
Athletics
|
|
193 |
| 2018 Winter Olympics |
Ukraine
|
Olena Pidhrushna
|
Biathlon
|
|
57 |